Analysis of the Polymer Type of Nylon 6 (Polyamide 6)
1. Chemical Nature
Repeating Unit Characteristics: The Nylon 6 molecular chain is composed of amide bonds (-CONH-) and 5 methylene groups (-CH₂-) in a repeating cycle, belonging to the linear polyamide family.
Polymerization Mechanism: Formed through the ring-opening polymerization of caprolactam (different from the dual-monomer condensation polymerization of Nylon 66 ).
2. Material Category
Thermoplastic: Can be heated and molded multiple times (injection molding/extrusion), and waste can be recycled.
Semi-crystalline Polymer: During cooling, some molecules are arranged in an orderly manner (crystallinity approximately 40-50%), providing high rigidity and heat resistance.
3. Performance Positioning
| Characteristic | Nylon 6 Attributes | Performance Benchmark |
|---|---|---|
| Strength & Toughness | Medium-high strength engineering plastic | Outperforms PP/ABS, underperforms metals |
| Heat Resistance | Melts at 220°C; long-term use <80°C | Lower than PEEK, higher than commodity plastics |
| Moisture Absorption | High hygroscopicity (swells when wet) | Far exceeds PC/PS; requires dry storage |
4. Functional Application Classification
Self-lubricating Material: Molecules contain polar groups, resulting in a low coefficient of friction (0.3-0.5), suitable for oil-free gears/bearings.
Dielectric Material: Good insulation in a dry state (drops sharply when wet), used in electrical connectors.
Low-temperature Toughness Material: Maintains elasticity at -40℃, commonly used in ski equipment bindings.
5. Modified Derivative Types
Reinforced Type: Addition of glass fiber → structural engineering plastic (e.g., PA6 GF30).
Toughened Type: Incorporation of elastomers → impact-resistant components (bicycle helmet buckles).
Conductive Type: Mixing with carbon fiber → anti-static equipment casings.

